Developing photosensitizers suitable for the cobalt electrolyte and understanding the structure-property relationship of organic dyes is warranted for the dye-sensitized solar cells （DSSCs）. The DSSCs incorporating tris（1,10-phenanthroline）eobalt（Ⅱ/Ⅲ）-based redox elec- trolyte and four synthesized organic dyes as photosensitizers are described. The photovoltaic performance of these dyes-sensitized solar cells employing the cobalt redox shuttle and the influences of the w-conjugated spacers of organic dyes upon the photovoltage and photocur- rent of mesoscopic titania solar cells are investigated. It is found that organic dyes with thiophene derivates as linkers are suitable for DSSCs employing cobalt electrolytes. DSSCs sensitized with the as-synthesized dyes in combination with the cobalt redox shuttle yield an overall power conversion efficiency of 6.1% under 100 mW/cm2 AM1.5 G illumination.
