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Rheological and mechanical properties of wood fiber-PP/PE blend composites被引量:9
2008年
For evaluation of the rheological and mechanical properties of highly filled wood plastic composites (WPCs), polypropylene/polyethylene (PP/PE) blends were grafted with maleic anhydride (MAH) to enhance the interfacial adhesion between wood fiber and matrix. WPCs were prepared from wood fiber up to 60 wt.% and modified PP/PE was blended by extrusion. The rheological properties were studied by using dynamic measurement. According to the strain sweep test, the linear viscoelastic region of composites in the melt was determined. The result showed that the storage modulus was independent of the strain at low strain region (〈0.1%). The frequency sweep resuits indicated that all composites exhibited shear thinning behavior, and both the storage modulus and complex viscosity of MAH modified composites were decreased comparing to those unmodified. Flexural properties and impact strength of the prepared WPCs were measured according to the relevant standard specifications. The flexural and impact strength of the manufactured composites significantly increased and reached a maximum when MAH dosage was 1.0 wt%, whereas the flexural modulus after an initial decreased, also increased with MAH dosage. The increase in mechanical properties indicated that the presence of anhydride groups enhanced the interracial adhesion between wood fiber and PP/PE blends.
高华宋永明王清文韩振张明丽
关键词:COMPOSITES
抗冲改性剂ACR对发泡木粉-PVC复合材料熔体流变性能的影响被引量:1
2009年
采用旋转流变仪及小振幅流变测量法,研究了冲击改性剂ACR对发泡木粉-PVC复合材料熔体流变性能的影响。结果表明:①发泡木粉-PVC复合材料熔体表现出黏弹性。②加入5份ACR,发泡木粉-PVC复合材料熔体的储能模量G′和损耗模量G″随角频率ω增大而增加;在相同ω时,G′和G″随ACR用量增加而降低;随ω增大,加入ACR使木粉-PVC复合材料熔体的弹性响应增加。③加入5份ACR,明显促进了PVC的凝胶化。发泡木粉-PVC复合材料熔体的复数黏度η*随角频率ω增大而降低;加入5份ACR,其η*明显高于其他ACR用量的熔体,复合材料的冲击强度增加26%,提高幅度最大。④ACR在改善发泡木粉-PVC复合材料冲击强度和加工流变性能方面,具有添加量少、效果明显的特点。
白晓艳王清文王海刚韩振李中秋
关键词:流变性能
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