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国家自然科学基金(20103007)

作品数:2 被引量:10H指数:1
相关作者:黄锐杨鸣波李忠明杨伟冯建民更多>>
相关机构:四川大学更多>>
发文基金:国家自然科学基金四川省应用基础研究计划项目更多>>
相关领域:化学工程理学更多>>

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Coupling Among CH Stretching, Bending and Rocking Vibrational Modes in CH2Cl2
2006年
Infrared absorption spectra of gaseous CH2Cl2 in the regions of 1200-12000 cm^-1 were measured using a Bruker IFS 120HR Fourier transform spectrometer in conjunction with a nmltipass cell. 47 vibrational levels of overtone and combinational spectral lines of the CH stretching (v1, v6), bending (v2), and rocking (v8) modes were analyzed and assigned. Utilizing the normal mode model and considering the coupling among CH stretching, bending and rocking vibrations, values of the harmonic frequency wi, the anharmonic constant xij, and the coefficients of Fermi and the Darling-Dennison resonances of v1, v6, v2 and v8 modes were also determined from experimental spectral data with nonlinear least-square fitting. These spectral constants reproduced the experimental levels very well. These results showed that Fermi resonance between CH stretching and rocking vibrations (kiss=-254.63 cm^-1) is stronger than that between CH stretching and bending vibrations (k122 = 54.87 cm^-1 ); and that Darling-Dennison resonances between CH stretching and bending vibrations (k166=-215.28 cm^-1) is also much stronger than that between CH bending and rocking vibrations (k2288=5.72 cm^-1).
Qing-hua LiuXiao-ning LiLu-yuan HaoChuang TanYin-gui ZhouPing ChenHuai Zhu
GEP/PO原位微纤化共混物的制备被引量:10
2003年
利用"熔融挤出-热拉伸-淬冷"方法制备了几种通用工程塑料(GEP)/聚烯烃(PO)原位微纤化共混物,研究了加工设备(挤出机、注塑机、HAAKE流变仪附属单螺杆挤出机)和口模结构(窄缝状、片状、棒状)对聚对苯二甲酸乙二醇酯(PET)/聚乙烯(PE)共混物原位成纤的影响,发现带矩形窄缝状口模的挤出机挤出能产生更好的纤维结构,而有高剪切作用的对空注塑不能形成纤维结构。观察PET/PE,PET/聚丙烯(PP),聚碳酸酯(PC)/PE及PC/PP共混物的成纤情况,发现通常认为不利于成纤(粘度比大于1)的PC/PE和PC/PP体系也形成了较好的纤维形态。总体上,PET/PE的成纤效果好于其它的体系。
李忠明杨伟谢邦互杨鸣波黄锐冯建民
关键词:熔融挤出工程塑料聚烯烃
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