In ethanol, the copper(II) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with cell constants, a=2.273 6(4) nm, b=0.592 12(9) nm, c=1.828 1(3) nm, β=109.735(5)°, V=2.316 4(7) nm3, Z=4, μ=1.164 mm-1, Dc=1.595 g·cm-3, F(000)=1 140, R=0.048 6, wR=0.101 6. In the compound copper(II) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. Their biological activities have been measused. The results show that the anti-bacterial activity of the coordination compound is much better that of the ligand. CCDC: 272938.
The title compound was synthesized by the reaction of 3-benzoxybenzaldehyde with 2-hydroxybenzoylhydrazine in ethanol and characterized by IR,UV,1H NMR spectra and elemental analysis.The single crystal structure was determined by X-ray diffraction analysis.The crystal belongs to Monoclinic system,space group Cc with cell constant,a=0.48217（11） nm,b=3.2212（7） nm,c=1.0992（3） nm,β=101.755（5）.,V=1.6714（7） nm3,Z=4,μ=0.090mm-1,DC=1.321 g/cm3,F（000）=696.The crystal measurement showed that the molecule was not coplanar.The crystal structure involving in intermolecular and intermolecular hydrogen bonds was observed,and the intermolecular hydrogen bonds are linked along the c-axis direction to form a chain.The title molecule was calculated by quantum chemistry at the RHF/6-31G level,frontier orbitals electronic densities and charge distribution were discussed.
