In this paper,the bi-functional catalyst system composed of molecular sieve(MCM-41) immobilized oligomerization catalyst(C25H17Cl2N3·FeCl2) and copolymerization catalyst(Et(Ind)2ZrCl2) was employed in the in situ copolymerization of ethylene aiming to prepare the Linear low density polyethylene(LLDPE).In this paper,we mainly argued the regular pattern of the in situ copolymerization of ethylene in limited nano-space and compared it with that happening in free space.The impact of variance of the reaction temperature,Fe/Zr value and the A1/(Fe+Zr) value on the activity of the in situ copolymerization of ethylene has also been introduced.Furthermore,the degree of branching,thermal properties and crystalline changes of the obtained polymerization products prepared from different reactivity were investigated.
We have used a unique process to develop the first successful anion rubber modified asphalt mixture.Rubber and asphalt are used in equal proportions in the mix.Compared with conventional asphalt,the anion rubber modified asphalt show better pavement performance,and fully met the relevant specifications.The dynamic stability and failure strain indicators are better than those of SBS modified asphalt.Compared with traditional rubber modified asphalt,the amount of waste tires incorporated into this new rubber modified asphalt is much greater;the new asphalt also improved the air quality near the road,thus providing great economic and social benefits.
HONG WeiLI QingShanGUAN GuoQuanLIU JunSUN JingXING GuangZhong
