In laser welding-brazing of Al alloy (5A06) and Ti alloy (Ti-6Al-4V) with rectangular CO2 laser spot and with Al-12Si filler wire, element Si enriches at the interface between Ti substrate and the filler metal. It is found that the Si diffusion behavior has a significant effect on the formation of interfacial intermetallic compounds. To analyze the Si diffusion behavior, a model for the prediction of the chemical potential for ternary alloy was established. According to the calculated results of the influence of the element content and temperature in Ti-Al-Si system on Si chemical potential, the diffusion behavior of Si element was analyzed for Ti dissolution and melting mode, which presents a good agreement with the experimental data. Further, formation mechanism of the interfacial intermetllic compound was clarified.
The flange butt joints of 1 mm-thick galvanized steel sheets were brazed with CuSi3 as filler metal at different laser heating modes.The microstructures and element distributions of joint interface were investigated by SEM and EDS.The results show that there is no obvious interface layer with the circular individual beam heating and lamellar Fe-Si intermetallic compound layer is found with dual-beam laser spot heating.With the irradiation of rectangular laser spot,the joint interface layer is also formed.The layer thickness is larger than that of dual-beam brazing and the layer shape is flat so that intermetallic compounds trend to grow into cellular crystals.Moreover,the interface layer shape also depends on its position in the joint.Under the high heat input,dendritic or granular intermetallic compounds dispersively distribute in brazing seam adjacent to the interface,which is caused by the melting or dissolving of the base metal.According to the results,the brazing quality can be controlled by laser heating mode and processing parameters.