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国家自然科学基金(41272149)

作品数:4 被引量:15H指数:3
相关作者:刘虎张海祖廖泽文程斌田彦宽更多>>
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受生烃母质控制的干酪根及其热解产物稳定碳同位素分布模式被引量:5
2016年
塔里木盆地来源于寒武系—下奥陶统烃源岩的原油与其母质干酪根的稳定碳同位素存在倒转现象,为验证这种同位素倒转并探讨其可能原因,选取华北下花园地区的下马岭组灰质页岩和泥质页岩,以及新疆三塘湖盆地的芦草沟组泥质页岩样品开展热模拟实验。结果在下马岭组灰质页岩干酪根热解残渣和其热解油之间发现了这种碳同位素的倒转分布。与未发现碳同位素倒转现象的下花园地区和三塘湖盆地的泥质页岩样品相比,下马岭组灰质页岩干酪根热解油的稳定碳同位素变化幅度相对较大,而残渣的碳同位素变化幅度相对较小。结合有机岩石学及生物标志化合物综合分析发现,下马岭组灰质页岩中间隔分布的"下花园藻残片"生烃能力相对较差,且几乎没有检测到甾、萜类生物标志化合物;而在另外两组泥岩的热解产物中并没有发现这种现象,显示了下马岭组灰质页岩具有特殊的母质类型或沉积环境。由此可见,下马岭组灰质页岩干酪根及其热解产物之间的稳定碳同位素倒转分布很可能与早期生命体特殊的生物化学组成,或者早期的类异戊二烯烃类在沉积过程中更难以被保存下来等因素有关。
刘虎廖泽文戚明辉张海祖杜军艳杨珊
关键词:热模拟实验干酪根
Comprehensive diag”nostic review of the (13)~C-enriched crude oils exemplified by TD2∈ and TZ62S in Tarim Basin, NW China被引量:3
2015年
The crude oils typically from the CambrianLower Ordovician source rocks of Tarim Basin, NW"China, such as TD2 and TZ62S, are13C-enriched with the stable carbon isotopic ratios(VPDB) approaching-28 %.In this paper, the main research viewpoints on this issue are summarized, and combined with results from organic and inorganic carbon isotope stratum curves of the outcrop at the Ya'erdang Mountain in Tarim Basin. In addition, more alternative interpretations are discussed. On one hand, the inverse fractionation features of stable carbon and hydrogen isotopes of these crude oils may imply their protogenous nature. On the other hand, the anisotropy of source rocks and contribution from older stratum source rocks need verifying as well. For the sake of the final resolution of this issue, some further study topics are recommended.
Hu LiuZewen LiaoHaizu ZhangYankuan TianBin ChengXiaohong Chang
关键词:塔里木盆地原油审查
干酪根及其演化产物中稳定碳同位素的倒转分布--研究进展及对塔里木盆地海相油气藏研究的启发被引量:10
2013年
本文从干酪根及其演化产物中稳定碳同位素倒转分布的研究进展出发,将地质历史中沉积有机质稳定碳同位素的倒转分布按其赋存载体的不同概括为两种类型,即烃源岩可溶组分或原油族组分(饱和烃、芳烃、非烃、沥青质)之间的稳定碳同位素倒转分布,以及烃源岩可溶组分或原油与母质干酪根之间的稳定碳同位素倒转分布。重点综述了后者的两种成因机制——演化论和源控论,结合塔里木盆地古生界两套海相主力烃源岩的研究进展,探讨塔里木盆地典型源自寒武系-下奥陶统烃源岩原油异常富集13 C并与其母质干酪根发生稳定碳同位素的高程度倒转分布在源控论方面的可能证据和地球化学意义,进一步丰富和深化针对塔里木盆地海相油气藏的相关研究。
刘虎廖泽文张海祖程斌田彦宽
关键词:干酪根稳定碳同位素塔里木盆地
Stable isotope(δ^(13)C_(ker),δ^(13)C_(carb),δ^(18)O_(carb)) distribution along a Cambrian outcrop section in the eastern Tarim Basin,NW China and its geochemical significance被引量:1
2017年
This study investigated the geochemical features of the lower Paleozoic strata of Yaerdang Mountain outcrop along with the core samples from well TD2∈ in the eastern Tarim Basin,NW China.The total organic carbon abundance,hydrocarbon-generating precursor biospecies,and stable isotope ratios of organics and carbonate(δ^(13)C_(ker),δ^(13)C_(carb) and δ^(18)O_(carb)) were comprehensively studied for their possible correlative constraints during sedimentary evolution.The results revealed that the δ^(13)C_(ker)(VPDB) of Cambrian kerogens along the outcrop section varied from-34.6‰ to-28.4‰,indicating an increasing tendency from the lower Cambrian to the upper Cambrian.This was on the whole accompanied by the variation in the δ^(13)C_(carb) and δ^(18)O_(carb) along the profile,which might be associated with the changes in the sea level and also in the compositional variation of benthic and planktonic biomass.The large variation in the stable carbon isotope ratios up to 6‰ along the outcrop section reflected the heterogeneity of the Cambrian source rocks from the eastern Tarim Basin.Hence,the ^(13)C-enriched crude oils from well TD2∈might have been derived from a localized stratum of Cambrian source rocks.The results from this study showed the possibility of multiple source kitchens in the Cambrian-lower Ordovician portion of Tarim Basin.
Hu LiuZewen LiaoHaizu ZhangYankuan TianBin ChengShan Yang
关键词:KEROGENHETEROGENEITY
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