Lightweight magnesium alloy has recently attracted a considerable interest in the automotive and aerospace industries to improve fuel efficiency and reduce CO2 emissions via the weight reduction of vehicles.Rare-earth(RE) element addition can remarkably improve the mechanical properties of magnesium alloys through weakening crystallographic textures associated with the strong mechanical anisotropy and tension-compression yield asymmetry.While the addition of RE elements sheds some light on the alteration in the mechanical anisotropy,available information on the constitutive relationships used to describe the flow behavior of RE-containing magnesium alloys is limited.To establish such a constitutive relationship,uniaxial compressive deformation tests were first conducted on an extruded Mg-10Gd-3Y-0.5Zr(GW103K) magnesium alloy at the strain rates ranging from 1×10–1 to 1×10–4s–1 at room temperature.A modified Johnson-Cook constitutive equation based on a recent strain hardening equation was proposed to predict the flow stresses of GW103K alloy.Comparisons between the predicted and experimental results showed that the modified Johnson-Cook constitutive equation was able to predict the flow stresses of the RE-containing magnesium alloy fairly accurately with a standard deviation of about 1.8%.
The microstructure, the content of compounds, mechanical properties and fracture behavior of high vacuum die casting Mg-8Gd-3Y-0.4Zr alloy (mass fraction, %) under T4 condition and T6 condition were investigated. The microstructure for the as-cast Mg-8Gd-3Y-0.4Zr alloy mainly consists ofα-Mg and eutectic Mg24(Gd,Y)5 compound. After solution treatment, the eutectic compounds dissolve massively into the Mg matrix. The main composition of solution-treated alloys is supersaturated α-Mg and cuboid-shaped phase. The T4 heat treated samples have increasing cuboidal particles with the increase of heat treatment temperature, which turn out good mechanical properties. The optimum T4 heat treatment for high vacuum die cast Mg-8Gd-3Y-0.4Zr alloy is 475 ℃, 2 h according to microstructure results. The optimum ultimate strength and elongation of solution-treated Mg-8Gd-3Y-0.4Zr alloy are 222.1 MPa and 15.4%, respectively. The tensile fracture mode of the as-cast, and T6 heat treated alloys is transgranular quasi-cleavage fracture.
Based on the cellular automaton (CA) method, a numerical model was developed to simulate the dendritic growth of magnesium alloy with HCP crystal structure. The growth kinetics was calculated from the complete solution of the transport equations. By defining a special neighborhood configuration with the square CA cell, and using a set of capturing rules which were proposed by BELTRAN-SANCHEZ and STEFANESCU for the dendritic growth of cubic crystal metals during solidification, modeling of dendritic growth of magnesium alloy with different growth orientations was achieved. Simulation of equiaxed dendritic growth and columnar dendritic growth under directional solidification was carried out, and validation was performed by comparing the simulated results with the experimental results and those in the previously published works.
Under the cold-chamber high pressure die casting (HPDC) process, samples were produced with AM60B magnesium alloy to investigate the microstructure characteristics of the eutectics, especially focusing on the constitution, morphology and distribution of the eutectics over cross section of the castings. Attentions were also paid to study the effect of heat treatment on the eutectics in the die castings. Based on experimental analysis using optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS), it was determined that fully divorced eutectics consisting of c^-Mg and l%MglzA112 appeared at the grain boundary of the primary c^-Mg in the as-cast microstructure. Islands and networks of β-Mg17Al12 phase were observed in the central region of the castings, while the β-Mg17Al12 phase revealed a more dispersed and granular morphology on the surface layer. The two phases ratio β/α in the central region of the castings was approximately 10%, which was higher than that on the surface layer. Besides, the defect bands contained a higher percentage of the eutectics than the adjacent regions. After aging treatment (T6), only α-Mg phase was detected by XRD in the AM60B magnesium alloy, though a small amount of precipitated β-MgITAI12 phase was observed at the grain boundary. In contrast to the microstructure of die cast AZ91D magnesium alloy under the same T0 heat treatment, no discontinuous precipitation of the β-MgITAI12 phase was observed in AMO0B magnesium alloy die castings.