Long-range surface plasmon polariton （LRSPP） modes in an asymmetrical system, in which the thin metal film is sandwiched between a semi-infinite substrate and a high permittivity polymer film with a finite thickness, are theoret~ ically calculated and analyzed. Due to the high permittivity of the polymer film, at proper polymer film thicknesses, the index-matching condition of the dielectrics at both sides of the metal can be satisfied for supporting LRSPP modes, and the electromagnetic field above the metal can be localized well. It is found that these LRSPP modes have both long propagation lengths and subwavelength mode expansion above the metal at the optimal polymer film thickncsses. Furthermore, the requirements on the refractive index and the thickness of the polymer film to support LRSPP modes at the optimal thicknesses are found to be not critical.
This paper investigates the third-order nonlinear optical properties of two azo-nickel chelate compounds by the optical Kerr gate method at 830 nm wavelength with pulse duration of 120 fs. Both of the two compounds exhibited large third-order optical nonlinearity. The second-order hyperpolarizability,γ, of Compound 1 is of 1.0 × 10^-31 esu. Due to the charge transfer, the γ of Compound 2 with electron donor and acceptor group is 4.9 × 10^-31 esu, which is a four-time enhancement in comparison with Compound i. The absorption spectra show that the electron push-pull effect, which induces intramolecular charge transfer, leads to the increased optical nonlinearity.
