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国家自然科学基金(41322016)

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松辽盆地庆深气田异常氢同位素组成成因研究被引量:5
2014年
对松辽盆地徐家围子断陷庆深气田天然气组分、碳氢同位素和稀有气体同位素的分析表明,天然气以烷烃气为主,烷烃气碳同位素组成随着碳数增加呈变轻趋势,且δ13C1>-30‰, R/Ra一般大于1.0,δ13CCO2值介于-16.5‰~-5.1‰之间;氢同位素组成δD1=-205‰~-197‰,平均值为-203‰,δD2=-247‰~-160‰,平均值为-195‰,δD3=-237‰~-126‰,平均值为-163‰,且存在氢同位素组成倒转现象,即δD1>δD2<δD3。根据对庆深气田天然气不同地球化学特征分析,认为该气田烷烃气中重烃主要为有机成因,而 CH4有相当无机成因混入。庆深气田烷烃气氢同位素组成具有 CH4变化小,而重烃(δD2,δD3)变化大的特点。根据与朝阳沟地区天然气烷烃气氢同位素组成对比分析,认为 CH4主要表现为无机成因,而重烃气(δD2,δD3)主要为有机成因,且无机成因CH4氢同位素组成重于有机成因CH4。
刘全有戴金星金之钧李剑周庆华冯子辉孙红军
关键词:天然气氢同位素组成地球化学庆深气田
Potential petroleum sources and exploration directions around the Manjar Sag in the Tarim Basin被引量:7
2017年
Since the discovery of the Tahe oilfield,it has been controversial on whether the main source rock is in the Cambrian or Middle-Upper Ordovician strata.In this paper,it is assumed that the crude oil from the Wells YM 2 and TD 2 was derived from the Middle-Upper Ordovician and Cambrian source rocks,respectively.We analyzed the biomarkers of the crude oil,asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions from the Lunnan and Hade areas in the North Uplift of the Tarim Basin.Results show that the ratios of tricyclic terpane C_(21)/C_(23)in the crude oil,asphalt-adsorbed hydrocarbon and saturated hydrocarbon in bitumen inclusions are less than 1.0,indicating that they might be from Upper Ordovician source rocks;the ratios of C_(28)/(C_(27)+C_(28)+C_(29))steranes in the saturated hydrocarbon from reservoir bitumen and bitumen inclusions are higher than 25,suggesting that they might come from the Cambrian source rocks,however,the ratios of C_(28)/(C_(27)+C_(28)+C_(29))steranes in oil from the North Uplift are less than 25,suggesting that they might be sourced from the Upper Ordovician source rocks.These findings demonstrate that the sources of crude oil in the Tarim Basin are complicated.The chemical composition and carbon isotopes of Ordovician reservoired oil in the Tarim Basin indicated that the crude oil in the North Uplift(including the Tahe oilfield)and Tazhong Depression was within mixture areas of crude oil from the Wells YM 2 and TD 2 as the end members of the Cambrian and Middle-Upper Ordovician sourced oils,respectively.This observation suggests that the crude oil in the Ordovician strata is a mixture of oils from the Cambrian and Ordovician source rocks,with increasing contribution from the Cambrian source rocks from the southern slope of the North Uplift to northern slope of the Central Uplift of the Tarim Basin.Considering the lithology and sedimentary facies data,the spatial distribution of the Cambrian,Middle-Lower Ordovician and Upper Ordovician source rocks was reconstructed
JIN ZhiJunLIU QuanYouYUN JinBiaoTenger
关键词:满加尔凹陷中上奥陶统地层原油储层沥青
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