A direct electroless copper （Cu） coating on tungsten powders method requiring no surface treatment or stabilizing agent and using glyoxylic acid （C2H203） as a reducing agent was reported. The effects of copper sulfate concentration and the pH of the plating solution on the properties of the prepared W@Cu composite powders were assessed. The content of Cu in the composite powders was controlled by adjusting the concentration of copper sulfate in the electroless plating solution. A uniform, dense, and consistent Cu coating was obtained under the established optimum conditions （flow rate of C2H203 = 5.01 mL/min, solution pH = 12.25 and reaction temperature 45.35℃） by using central composite design method. In addition, the crystalline Cu coating was evenly dispersed within the W@Cu composite powders and Cu element in the coating existed as Cu~. The formation mechanism for the W@Cu composite powders by electroless plating in the absence of surface treatment and stabilizing agent was also proposed.
采用多介质弹塑性流体动力学计算方法,研制了适用于复杂加载的Lagrange计算程序MLEP,对劳伦斯利弗莫尔国家实验室(Lawrence Livermore National Laboratory,LLNL)19层和冲击波物理与爆轰物理国防科技重点实验室(Laboratory of Shock Wave andDetonation Physics,LSD)设计的29层Mg-Cu体系Pillow密度梯度飞片气炮加载实验过程进行了数值模拟和比较,获得的速度剖面计算结果与实验测试结果吻合一致,验证了流体动力学计算方法、不同材料体系混合模型以及计算程序的有效性和实用性,为进一步开展可控路径的复杂加载实验研究奠定了基础。
Two types of Mg-Cu composition system graded density impactors used for complex loading (shock loading and quasi-isentropic compression) are designed by the elastic-plastic hydrodynamic method in this paper. Mixtures of metal powders in the Mg-Cu system are cast into a series of 17 and 25 uniform compositions ranging from 100% Mg to 100% Cu. The graded density impactors are launched to the stationary 10 m aluminum film and 12 mm LiF window targets by a two-stage light-gas gun in the National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, and the resulting wave profiles are measured with the DISAR system. Hydrodynamic simulation results are perfectly consistent with the experiments. Our work in this paper will set up a foundation for further research of controllable loading/releasing routes and rate experiments in the future.
BAI JingSongTANG MiLUO GuoQiangYU JiDongYUAN ShuaiDAI ChengDaWU QiangTAN Hua
