浙江省自然科学基金(Y4100579)
- 作品数：1 被引量：10H指数：1
- 相关作者：徐清李强更多>>
- 相关机构：温州大学更多>>
- 发文基金：浙江省自然科学基金国家自然科学基金更多>>
- 相关领域：理学更多>>
- Copper-Catalyzed C-Alkylation of Secondary Alcohols and Methyl Ketones with Alcohols Employing the Aerobic Relay Race Methodology
- Alcohols are a class of green chemicals in many aspects.1 In addition to the N-alkylation reactions,they have ...
- Shiheng Liao and Qing Xu* College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035
- 关键词：ALCOHOLSC-ALKYLATION
- 文献传递
- Copper-Catalyzed N-Alkylation of Amides and Amines with Alcohols Employing the Aerobic Relay Race Methodology
- Copper catalysts have received broad interests and utilities in both academy and industry for their many advan...
- Qiang Li and Qing Xu* College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035
- 关键词：ALCOHOLSN-ALKYLATION
- 文献传递
- General and Advantageous Air-Promoted Metal-Catalyzed Aerobic N-Alkylation of Amides and Amines with Alcohols
- <正>Alcohols are a class of green chemicals in many aspects.1 In recent years,as frequently highlighted by the ...
- Qing Xu* College of Chemistry and Materials Engineering,Wenzhou University,Wenzhou 325035
- 关键词：ALCOHOLSN-ALKYLATION
- 文献传递
- 过渡金属催化醇与胺有氧脱水反应及相关研究进展被引量：10
- 2013年
- 与其他胺和酰胺衍生物的合成方法相比,过渡金属催化醇与各类胺和酰胺的脱水N-烷基化反应是一种相对绿色、原子经济性较高的方法,一般被称为"借氢"或"氢自动转移"反应及其方法学.近年来,在空气氛围下过渡金属催化醇与胺和酰胺的有氧脱水N-烷基化反应,可使用更稳定的金属催化剂、可在无配体、空气等更温和简单的条件下进行,也引起了人们的极大关注.主要介绍近年来过渡金属催化下醇与胺和酰胺在空气或者氧化剂作用下构建C—N,C=N键合成胺和酰胺衍生物以及亚胺类化合物的有氧脱水反应进展情况,同时也对相关有氧脱水C-烷基化反应进行简单介绍.相关反应的机理研究也将作适当讨论.
- 徐清李强
- 关键词：过渡金属催化N-烷基化反应
- Palladium- or Copper-Catalyzed Aerobic Oxidative Synthesis of Imines from Alcohols and Amines under Ambient Conditions
- Imines are a class of nitrogen compounds of high significance in chemistry.For the high reactivity of the C=N ...
- Haiwen TianLan JiangXiaochun YuQing Xu
- 关键词：IMINESALCOHOLSAMINESAEROBICOXIDATIVE
