The complex [Zn(acac)2(C5H4NOH)] was synthesized based on the reaction of zinc(Ⅱ)acetate,acetylaceton and 3-hydroxypyridine(C5H4NOH)in methanol medium.The structure of the complex was confirmed by IR,1H NMR,elemental analysis,thermal analysis and X-ray single crystal diffraction.The crystal belongs to monoclinic system with space group P21/n,and a=0.743 7(3)nm,b=0.829 5(3)nm,c=2.612 5(9)nm,β=95.026(6)°,V=1.605 4(9)nm3;Dc=1.484 g·cm-3;Z=4;F(000)=744;μ=1.551 mm-1.Zinc(Ⅱ)atom lies at the center of an coordination of the distorted square pyramidal formed by four O atoms which come from two different acetylaceton ions and one N atom from the 3-hydroxypyridine molecule.CCDC:600232.
A mixed complex [Zn(CF3COO)2(C7H6NS)2] was synthesized based on the reaction of Zn(CF3COO)2 and 2-aminobenzothiazol (C7H6NS) in methanol. The structure of the complex was characterized by elemental analysis, IR, 1H NMR and thermal analysis. The crystal structure of the complex was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic system with space group C2/c, a=3.174 3(9) nm, b=1.010 0(3) nm, c=1.723 1(5) nm, β=118.841(4)°, V=4.839(2) nm3; Dc=1.625 g·cm-3; Z=8; F(000)=2 368; μ=1.266 mm-1. CCDC: 600233.
