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国家自然科学基金(21177087)

作品数:13 被引量:63H指数:5
相关作者:程金平王文华江璇朱琼宇薄丹丹更多>>
相关机构:上海交通大学上海市环境保护局东华大学更多>>
发文基金:国家自然科学基金教育部“新世纪优秀人才支持计划”国家重点基础研究发展计划更多>>
相关领域:环境科学与工程医药卫生理学生物学更多>>

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13 条 记 录,以下是 1-10
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霾与非霾期间汞在不同粒径颗粒物上的分布特征被引量:9
2015年
在我国高速经济增长过程中,霾污染日趋突出,同时大气汞污染也十分严重,而颗粒汞对于汞在大气中的循环演化意义重大.为了探讨霾污染期间汞在不同粒径颗粒物中的分布特征,采用Nano-moudi 12级(6.2~9.9μm、3.1~6.2μm,1.8~3.1μm、1.0~1.8μm、0.56~1.0μm、0.32~0.56μm、0.18~0.32μm、0.10~0.18μm,0.056~0.10μm、0.032~0.056μm、0.018~0.032μm、0.010~0.018μm)大气颗粒物采样器,对上海霾与非霾期间不同粒径大气颗粒物中的汞进行分析.结果表明,颗粒态汞含量与颗粒物含量正相关;采样期间霾天颗粒态汞平均浓度0.31 ng·m-3是非霾天颗粒态汞平均浓度0.11 ng·m-3的2~3倍;霾和非霾天颗粒态汞浓度以及颗粒物质量浓度随粒径分布呈双峰型,霾期间峰值分别出现在0.56~1.0μm粒径段和3.1~6.2μm粒径段,而非霾期峰值分别出现在0.32~0.56μm和3.1~6.2μm粒径段;霾天较非霾天颗粒态汞和颗粒物的粒径分布均出现了向大粒径方向偏移;颗粒态汞主要分布在粒径≤1μm粒子上,能够长时间停留和长距离输送;非霾期间颗粒态汞在颗粒物中的平均含量为0.029 ng·μg-1,而霾期间为0.015 ng·μg-1;霾污染过程中其他污染物迅速成长,而汞成长较慢;霾天积聚核模态粒子中颗粒态汞质量浓度为2.06 ng·m-3,而非霾天为0.55 ng·m-3,积聚态颗粒物的大幅增加,是灰霾形成的主要原因.本地源燃煤等的排放以及风沙扬尘的增加和外地源的输送是导致霾天污染严重的重要原因.
朱琼宇程金平魏雨晴薄丹丹陈筱佳江璇王文华
关键词:颗粒态汞粒径分布大气颗粒物ICP-MS
Degradation of Selected Indoor Air Pollutants:Comparison Study of Photocatalytic,Ozone-Assisted Photocatalytic and Amine Adsorption Processes被引量:3
2012年
Indoor air pollutants impact human health,comfort and productivity.The method of photocatalysis has been applied mainly in flow reactors and little information is available on indoor air pollutant removal in airtight reactors.In the paper,experiments were carried out to remove formaldehyde(HCHO),ammonia(NH_3) and volatile organic compounds(VOCs)in the airtight and ventilated chambers.Results demonstrated that 90.4%of HCHO,92.3%of NH_3 and 57.9%of VOCs were removed in the amine adsorption process,while 67.5% (hereinbefore,these are the mass fraction)of HCHO,60.0%of NH_3,and 61.2%of VOCs were removed in the photocatalytic process.However,ozone-assisted photocatalytic process showed great potential to degrade indoor air pollutants in the ventilated chamber.Factors and mechanisms of the photocatalytic degradation of HCHO, NH_3 and VOCs were also discussed.
赵文昌程金平陈颖王文华
Assessing Adverse Effects of Aroclor 1254 on Perinatally Exposed Rat Offspring
2015年
To assess the neurotoxic effects and redoxresponses of Aroclor 1254 (A1254) on perinatallyexposed rat offspring, A1254 was administered bygavage from gestational day (GD) 6 to postnatal day(PND) 21. Neurobehavioral development,antioxidant enzyme activities, lipid peroxidation(LPO), nitric oxide (NO), and NO synthase (NOS)levels were analyzed in the offspring.Neurobehavioral development analysis revealeddelayed appearance of the righting reflex, negativegeotaxis, and cliff drop test responses in A1254exposed group. Developmental A1254 exposurealso caused oxidative stress in the brain of PND 22offspring via reductions in the activity of SOD andGSH-Px, and by promoting a rise in the levels of NOand NOS.
TANG WeiCHENG Jin PingYANG Yi ChenWANG Wen Hua
关键词:PND
Mercury Exposures in Population from Tieling Coal Mine Area,Liaoning,China
2015年
Mercury( Hg) concentrations were determined in human hair,blood and urine samples from Tieling coal mine area,to assess the potential health risks associated with Hg due to coal mining activities. The total Hg levels in hair( average 0. 87 μg / g) and blood( average 3. 74 μg /L) of coal miners were quite low at around the same levels as the general population, but the urine Hg levels( average 12. 13 μg /L) were much higher than those from administrators and control group. This study indicated that workers mainly exposed to inorganic Hg through long-time inhalation contaminated air and dust; however other population mainly exposed to methylmercury( Me Hg).
唐蔚程金平赵文昌赵晓祥王文华
关键词:HAIRBLOODURINE
三种典型汞污染源暴露人群的发汞水平调查被引量:3
2014年
[目的]研究典型汞污染源暴露人群的发汞含量,为保护相关人群健康提供依据。[方法]收集浙江某电子废弃物回收区人群发样64份,辽宁某煤矿区人群发样145份、尿样145份,上海某医院医护人员发样62份。采用冷原子吸收法测定发总汞和尿汞含量,采用盐酸-甲苯萃取,气相色谱测定甲基汞含量。[结果]电子废弃物回收区人群中酸洗工人头发总汞含量为1.64μg/g,工业区管理人员为0.84μg/g;当地市民头发甲基汞含量为1.25μg/g,酸洗工人仅为0.23μg/g。辽宁铁岭煤矿区人群发汞含量为煤矿工人0.87μg/g、矿区管理人员0.65μg/g、当地居民0.60μg/g,上述3种人群的尿汞含量分别为12.13、2.74、2.14μg/L;上海某医院不同科室的医务人员发汞含量均低于美国环境保护署规定的发汞安全限值1.0μg/g。[结论]台州电子废弃物回收区和铁岭煤矿区工人存在一定的汞污染暴露风险。
唐蔚程金平赵晓祥冀秀玲王文华
关键词:发汞甲基汞
Assessing pre/post-weaning neurobehavioral development for perinatal exposure to low doses of methylmercury被引量:6
2015年
Fetuses and neonates are known to be high-risk groups for Methylmercury(MeHg)exposure.MeHg can be transferred to the fetus through the placenta and to newborn offspring through breast milk.The aim of the present study was to investigate the neurotoxic effects of low doses of MeHg(1 and 5 μg/m L in drinking water) administration,from gestational day 1 to postnatal day(PND) 21,on the neurobehavioral development of rats.The results showed that the no-observed-effect level of MeHg is somewhere in the range of 1-4 μg/mL.Neurobehavioral development analysis revealed a delayed appearance of cliff drop and negative geotaxis reflexes in the 5 μg/mL MeHg exposure group.Developmental exposure to MeHg affected locomotor activity functions for the females,but not for the males,implying that the female pups were more vulnerable than the male pups.All pups exposed to 5 μg/mL of MeHg showed a significant deficit in motor coordination in the rotarod test compared with controls,and the highest accumulated concentrations of Hg were found in the cerebellum,followed by the hippocampus and cerebral cortex,indicating that the cerebellum is a possible target for MeHg toxicity.We demonstrated adverse effects of developmental exposure to MeHg associated with tissue concentrations very close to the current human body burden of this persistent and bioaccumulative compound.
Jinping ChengMasatake FujimuraDandan Bo
关键词:METHYLMERCURY
上海市霾污染与长江口叶绿素a含量关系分析
2015年
近些年来霾污染日益严重,霾污染期间颗粒物浓度增加,在一定条件下颗粒物会通过干、湿沉降到海洋中,从而对海洋生态产生一定影响。为了探讨霾污染与海洋水环境中叶绿素a的关系,该研究通过对近1 a上海市10个环境监测站的PM2.5浓度和长江口43个监测站点叶绿素a浓度进行分析。结果表明,霾污染日叶绿素a平均浓度(2.52μg/L)高于非霾日(1.70μg/L)。霾日PM2.5浓度与叶绿素a浓度没有相关性(相关系数R2=0.048),轻度霾日和中度霾日叶绿素a浓度较高。对不同的霾周期分析可得,霾污染期间叶绿素a平均浓度与霾污染前相比,有所增加,主要表现在前期叶绿素a浓度减少,而后期叶绿素a浓度增加;霾消散后叶绿素a平均浓度与霾污染前相比则有所减少。由此推断,霾污染过程中海洋水环境中的叶绿素a浓度增加,但整个霾周期并不利于浮游植物的生长。
魏雨晴程金平印春生朱琼宇江璇王文华
关键词:PM2.5长江口叶绿素A
Experimental study on the uptake and effects of arsenic originated from poultry litter on the growth of Brassica napus in greenhouse pot cultivation and health risk assessment
2016年
Organoarsenics are widely used as growth promoters in poultry industry,resulting in arsenic(As)accumulation in poultry litter.A greenhouse pot study was implemented to investigate the fate of arsenic originated from poultry litter and their effects on the growth of Brassica napus(oilseed rape),and assess their potential health risks.Five poultry litter application rates(0,5%,10%,20%and 40%)were used,dividing into two groups:one for soil incubation(SI)and the other for plant cultivation(PC).Experimental results indicated that the total arsenic for composted poultry litter was(10.94±0.23)mg/kg,As(V)and As(III)decreased while methylated arsenic increased after 21 d in SI and PC treatments.Seed germination rates were negatively correlated with monomethylarsenic acid(MMA,R2=0.63,p<0.05).The length and biomass of roots and shoots were significantly inhibited by poultry litter,but plant length of 5%treatments was slightly stimulated.Within an average weekly intake of 0.5 kg Brassica napuss,the risk quotient(RQ)values induced from roots nearly all surpassed the acceptable limit(1),were two orders magnitude higher than shoots.According to the potential risk to order,child exhibited the highest risk,adolescent ranked secondly,and adult exhibited the lowest risk.Hence,people should better avoid intake Brassica napus roots to reduce arsenic potential risk.
Xie HaiyunHan DemingCheng JinpingWang LiangZhou PeiWang Wenhua
上海市霾与非霾期间PM_(2.5)中水溶性阳离子污染特征对比被引量:4
2014年
霾污染是颗粒物和气体污染物导致的可察觉到的能见度降低的天气污染现象,主要为PM2.5污染,水溶性阳离子是PM2.5的主要成分。为了探讨霾与非霾期间PM2.5水溶性阳离子污染特征,对上海市的PM2.5颗粒物连续采样1个月,利用离子色谱分析了K+、Na+、NH+4、Ca2+、Mg2+5种水溶性阳离子。结果表明,上海市霾天气期间PM2.5的日均质量浓度(103.03μg/m3)是非霾天气日均质量浓度(37.64μg/m3)的2.74倍,Na+、NH+4、Ca2+、Mg2+和K+的质量浓度分别为6.28、1.74、1.42、0.20和0.23μg/m3,PM2.5中水溶性阳离子组分占PM2.5质量浓度的20%左右。对大气气溶胶污染物、水溶性阳离子及气象因素相关性进行分析显示各污染物之间的相关性存在显著差异,其中NOX、NO和CO,SO2和NO2,Na+和CO,Mg2+和CO、NOX,可能存在共同来源。霾动态变化过程分析表明,水溶性阳离子浓度在霾与非霾天气时发生较大变化,Na+、Ca2+和Mg2+是霾天气的主要污染阳离子。
皮帅帅程金平刘淑娟黄娟王臻唐蔚王寅王文华
关键词:水溶性离子PM2.5
上海市中心城区主干道道路扬尘组分特征及来源解析被引量:26
2015年
分析了上海市中心城区主干道道路扬尘的化学组分,并采用化学质量平衡模型进行了道路扬尘的源解析。结果表明,上海市中心城区主干道道路扬尘的主要化学组分为Si(18.285 0%(质量分数,下同))、Ca(5.772 2%)、Al(2.460 6%)、Fe(2.345 8%)、Mg(0.889 3%)、K(0.846 4%)、Na(0.785 6%)等地壳元素;源解析结果表明,道路扬尘的首要污染来源是建筑尘(贡献率为34.4%),其次是土壤风沙尘(贡献率为32.6%)、渣土尘(贡献率为20.8%)、机动车尾气尘(贡献率为0.8%)。土壤风沙尘、建筑尘和渣土尘是道路扬尘主要的供应者(贡献率合计超过80%)。
陈筱佳程金平江璇朱琼宇魏雨晴薄丹丹
关键词:道路扬尘
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