One of the new directions in the field of Cretaceous research is to elucidate the mechanism of the sedimentary transition from the Cretaceous black shales to oceanic red beds. A chemical sequential extraction method was applied to these two types of rocks from southern Tibet to investigate the burial records of reactive iron. Results indicate that carbonate-associated iron and pyrite are relatively enriched in the black shales, but depleted or absent in red beds. The main feature of the reactive iron in the red beds is relative enrichment of iron oxides （largely hematite）, which occurred during syn-depostion or early diagenesis. The ratio between iron oxides and the total iron indicates an oxygen-enriched environment for red bed deposition. A comparison between the reactive iron burial records and proxies of paleo-productivity suggests that paleo-productivity decreases when the ratio between iron oxides and the total iron increases in the red beds. This phenomenon could imply that the relationship between marine redox and productivity might be one of the reasons for the sedimentary transition from Cretaceous black shale to oceanic red bed deposition.
Río Fardes剖面位于西班牙南部Granada东北,构造上属于深水环境的Subbetic中带。该剖面主要由白垩纪Fardes组第Ⅱ段和第Ⅲ段(半)远洋沉积构成,并出现浊流沉积和混杂沉积。本次研究在Fardes组浊流层序内首次发现两段红色沉积。钙质超微化石表明红层的时间从Turonian早期(UC7 带)到Coniacian中期—晚期界线(UC10/?UC11带)。红层由mm级红色泥岩夹灰色、杂色、偶尔黑色泥岩和钙质泥岩组成。沉积学研究表明新发现的Turonian Coniacian远洋红色泥岩沉积形成于CCD面之下深水盆地环境,浊流和碎屑流沉积强烈地影响着(半)远洋环境的背景泥岩相,并成为红色沉积结束的原因。
