The selective hydrogenolysis of C–O bond in furfural and its derivatives provides a sustainable route for transforming biomass-derived feedstocks into valued chemicals. Currently, the development of efficient catalysts which can effectively cleavage C–O bond under mild conditions remains a critical challenge. The present work reports Pt catalysts supported on multi-walled carbon nanotubes (MWNT) which are active in 2-methylfuran (2-MF) hydrogenolysis to form pentanols in liquid phase under mild conditions. The impact of various catalyst supports, active metals and reaction conditions in terms of metal loadings, solvent, time, pressure, etc., were explored.The 5 wt%Pt/MWNT catalyst demonstrated an excellent activity and selectivity with 100%2-MF conversion and53%pentanols (POLs) yield under 1 MPa H;at an exceptional low temperature of 25℃. The reaction mechanism was studied combing both the reactivity tests and characterization results, and it is found that the better catalytic performances of Pt/MWNT were correlated closely to the size of Pt nanoparticles and their interactions with the underlying MWNT support. Accordingly, a reaction pathway involving the adsorption of 2-MF parallel to the Pt nanoparticles and its subsequently selective C–O hydrogenolysis was proposed. This work showcases a promising catalyst for room-temperature biofuel production.
Ting WangBin ZhangChao-Qun YinJun ZhaoXiang LiuChuan Wang
This paper introduces an effective anti-icing strategy that uses passive anti-icing property and active de-icing functions concurrently.These dual capabilities can alleviate the icing problem more effectively than either a passive or active function alone.The developed material is a slippery liquid-repellent elastic conductor(SLEC);it is an organogel that is composed of multi-walled carbon nanotubes,oil,and polydimethylsiloxane.The SLEC maintains passive water-droplet sliding ability even on wet surfaces that frequently occur in cold conditions(e.g.,during condensation and defrosting),suppresses ice nucleation,and shows ice adhesion strength as low as^20 kPa.The SLEC releases heat when it is subject to electrical or photonic stimulation,and can therefore it can prevent ice formation and melt ice that has already formed on a surface.This material has sustainable liquid repellence by syneresis and replenishment;this ability ensures long-lasting anti-icing property,and results in exceptional durability.This durability is stable against mechanical damage.The superior dual anti-icing capabilities together with the sustainable and stable liquid repellence should generate synergistic effects,and yield a powerful anti-icing tool that can broaden the range of icing applications.
Aeree KimSeonghyeon KimMyoung HuhHyungmo KimChan Lee
