The systematic method for constructing Lewis representations is a method for representing chemical bonds between atoms in a molecule. It uses symbols to represent the valence electrons of the atoms involved in the bond. Using a number of rules in a defined order, it is often better suited to complicated cases than the Lewis representation of atoms. This method allows us to determine the formal charge and oxidation number of each atom in the edifice more efficiently than other methods.
Lahbib AbbasLahcen BihKhalid YamniAbderrahim ElyahyaouyAbdelmalik El AttaouiZahra Ramzi
The construction of advanced laboratories for precision instruments, such as electron microscopes, involves unique challenges that are influenced by the specific environmental conditions required for optimal functionality. These include mitigating interference from magnetic fields and vibrations, which are critical for maintaining the precision and accuracy of the instruments used. This study aims to offer enhanced project management strategies and detailed construction solutions that address the environmental and technical needs specific to electron microscopy labs, thereby facilitating effective lab operations and extending the lifecycle of high-end precision instruments. Case studies of existing laboratory constructions, onsite investigations, and comprehensive reviews of the technical and environmental requirements provide the basis for a best practice for constructing sophisticated electron microscopy labs. The approach integrates both pre-construction planning and post-construction adjustments to create optimal operational environments. The findings suggest that successful lab constructions are those that incorporate thorough onsite assessments, strategic location choices, and the use of advanced construction materials and techniques specifically designed to counteract environmental challenges like magnetic and vibration interferences. Actionable guidelines for both planning and executing the construction of electron microscope labs highlighted in this tutorial are intended as an important resource to troubleshoot or upgrade existing lab facilities and to consult in preparation of future lab construction projects.
Limei ChaMarkus Walkling-RibeiroZhenxi GuoYaron KauffmanConstance Van Horne
Utilizing granular computing to enhance artificial neural network architecture, a newtype of network emerges—thegranular neural network (GNN). GNNs offer distinct advantages over their traditional counterparts: The ability toprocess both numerical and granular data, leading to improved interpretability. This paper proposes a novel designmethod for constructing GNNs, drawing inspiration from existing interval-valued neural networks built uponNNNs. However, unlike the proposed algorithm in this work, which employs interval values or triangular fuzzynumbers for connections, existing methods rely on a pre-defined numerical network. This new method utilizesa uniform distribution of information granularity to granulate connections with unknown parameters, resultingin independent GNN structures. To quantify the granularity output of the network, the product of two commonperformance indices is adopted: The coverage of numerical data and the specificity of information granules.Optimizing this combined performance index helps determine the optimal parameters for the network. Finally,the paper presents the complete model construction and validates its feasibility through experiments on datasetsfrom the UCIMachine Learning Repository. The results demonstrate the proposed algorithm’s effectiveness andpromising performance.
Against the backdrop of the strategy to build a manufacturing powerhouse and the rapid development of integrated circuits(ICs),the emergence of new technologies,materials,and processes has rendered traditional IC reliability techniques inadequate for the evolving needs of IC development.Addressing the construction of an innovative IC reliability experiment platform has become a critical issue for scientific researchers at our city’s universities.This paper takes the Shenyang branch of the National Special Computer Research Center as a case study to explore how to optimize the construction of an IC reliability innovation platform.The discussion is structured around three dimensions:expanding the platform’s application scope,enhancing talent capabilities,and improving technological innovation levels.The findings are instrumental in elevating the standard of innovation platforms within the city.
We propose a method to construct Hopf insulators based on the study of topological defects from the geometric perspective of Hopf invariant I.Firstly,we prove two types of topological defects naturally inhering in the inner differential structure of the Hopf mapping.One type is the four-dimensional point defects.
Li-S batteries are regarded as one of the most promising candidates for next-generation battery systems with high energy density and low cost.However,the dissolution-precipitation reaction mechanism of the sulfur(S)cathode enhances the kinetics of the redox processes of the insulating sulfu r,which also arouses the notorious shuttle effect,leading to serious loss of S species and corrosion of Li anode.To get a balance between the shuttle restraining and the kinetic property,a combined strategy of electrolyte regulation and cathode modification is proposed via introducing 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoroprpyl ether(HFE)instead of 1,2-dimethoxyethane(DME),and SeS_(7)instead of S_8.The introduction of HFE tunes the solvation structure of the LiTFSI and the dissolution of intermediate polysulfides with Se doping(LiPSSes),and optimize the interface stability of the Li anode simultaneously.The minor Se substitution compensates the decrease in kinetic due to the decreased solubility of LiPSs.In this way,the Li-SeS_(7)batteries deliver a reversible capacity of 1062 and 1037 mAh g^(-1)with 2.0 and 5.5 mg SeS_(7)cm^(-2)loading condition,respectively.Besides,an electrolyte-electrode loading model is established to explain the relationship between the optimal electrolyte and cathode loading.It makes more sense to guide the electrolyte design for practical Li-S batteries.
The seven-membered ring motifs are found in bioactive pharmaceuticals and a wide range of natural products,including alkaloids and terpenoids,which hold significant importance in synthetic chemistry and has garnered considerable attention from both academia and industry.Despite the challenges faced in the past decade,the total synthesis of natural products incorporating the non-aromatic cycloheptane skeletons remains a compelling pursuit.Recently,numerous elegant strategies for constructing the sevenmembered ring system have been successfully developed.This review focuses on the recent advancements in this field from 2017 to April 2023,highlighting key transformations utilized to construct the non-aromatic cycloheptane core structures and serves as a valuable guide for synthetic chemists engaged in the total synthesis of natural products containing seven-membered ring motifs.
